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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

CAS: 95464-05-4

Molecular Formula: C35H24Cl4FeP2Pd

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex - Names and Identifiers

Name 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyms Pd(dppf)2Cl2
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichlorome
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE, DICHLOROMETHANE
DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]-PALLADIUM DICHLOROMETHANE ADDUCT
1'1-Bis(diphenylphosphino)fewocene Palladium(Ⅱ)chloride dichloromethane chloride
DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE ADDUCT
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct
DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE COMPLEX
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE COMPLEX
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride,complex with dichloromethane
CAS 95464-05-4
EINECS 619-128-9
InChI InChI=1/2C17H15P.CH2Cl2.2ClH.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;/h1-7,9-14H,8H2;1-14,17H;1H2;2*1H;/q;;;;;+2/p-2

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex - Physico-chemical Properties

Molecular FormulaC35H24Cl4FeP2Pd
Molar Mass810.59
Density1 g/cm3
Melting Point275-280°C(lit.)
Water SolubilityInsoluble in water.
Solubility Chloroform (Slightly), Methanol (Slightly)
Appearanceorange/red solid
Colororange-red
Storage ConditionKeep in dark place,Inert atmosphere,Room temperature
StabilityLight Sensitive
MDLMFCD00015757
UseApplied to palladium-catalyzed cross-coupling reactions

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex - Risk and Safety

Hazard SymbolsXn - Harmful
Harmful
Risk CodesR20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R40 - Limited evidence of a carcinogenic effect
R67 - Vapors may cause drowsiness and dizziness
R48/20/22 -
Safety DescriptionS23 - Do not breathe vapour.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 - Wear suitable protective clothing and gloves.
WGK Germany3
TSCANo
HS Code28439000

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex - Introduction

This product is useful for the borylation of triflate with pinacolborane.
Last Update：2022-10-16 17:30:21

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex - Reference Information

Introduction various phosphine Bridge transition binuclear complexes with bidentate phosphine ligands are mainly due to their special structure, because of its novel catalytic properties, ferrocene has attracted much attention due to its special molecular structure. 1,1 '-bis (diphenylphosphine) ferrocene (dppf) is a novel ligand that combines organic bidentate phosphine ligands with ferrocene, A wide variety of bimetallic and multimetallic complexes can be formed with another transition metal atom.
Application [1,1 '-bis (diphenylphosphino) ferrocene] Palladium dichloride methylene chloride complex is an organometallic compound, it can be used as a noble metal catalyst for carbonylation reaction, cross-coupling reaction, Suzuki reaction.
preparation Step 1: dissolve 2.00g of sodium chloropalladium in 30ml of absolute ethanol, step 2: dissolve 4.15G of 1,1 '-bis (diphenylphosphine) ferrocene in 41ml of dichloromethane to obtain 1, dichloromethane solution of 1'-bis (diphenylphosphine) ferrocene; Step 3: add the ethanol solution of chloropalladium sodium in step 1 Dropwise to step 2 under stirring condition, 1 '-bis (diphenylphosphine) ferrocene in methylene chloride solution, under the condition of the temperature of 25 deg C stirring reaction for 1H, after the reaction is filtered, 5.01g of crystals of orange-red [1,1'-bis (diphenylphosphino) ferrocene] Palladium dichloride dichloromethane complex are obtained in a yield of 90.46%. In this method, the target product of the solvent complex [1,1 '-bis (diphenylphosphine) ferrocene] Palladium dichloromethane complex was synthesized directly with dichloromethane as solvent in one step, the synthesis process of the precursor PdCl2(dppf) was omitted. The reaction process was simple, the synthesis cycle was short, and the operation was easy. The purity of the synthesized product was 99.4%, and the yield was 90.46%.
Application catalyst for carbonylation reaction, cross-coupling reaction, Suzuki reaction.
Last Update：2024-04-09 19:05:15
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
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Product Name: 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Request for quotation
CAS: 95464-05-4
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CAS: 95464-05-4
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Product Name: 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex Request for quotation
CAS: 95464-05-4
Tel:
Email: peilingchem@sina.com
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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
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